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| 5-[N-乙酸根(4-吡啶基)]四唑为桥联配体的铜(Ⅱ)、镉(Ⅱ)配聚物 | |
| 引用本文： | 杨高文,李巧云,王 君,袁荣鑫,谢吉民. 5-[N-乙酸根(4-吡啶基)]四唑为桥联配体的铜(Ⅱ)、镉(Ⅱ)配聚物[J]. 无机化学学报, 2007, 23(11): 1887-1894 |
| 作者姓名： | 杨高文 李巧云 王 君 袁荣鑫 谢吉民 |
| 作者单位： | 1. 常熟理工学院化学与材料工程系,江苏省新型功能材料重点建设实验室,常熟,215500 2. 常熟理工学院化学与材料工程系,江苏省新型功能材料重点建设实验室,常熟,215500;江苏大学化学化工学院,镇江,212013 3. 常熟理工学院化学与材料工程系,江苏省新型功能材料重点建设实验室,常熟,215500;南京大学配位化学研究所,配位化学国家重点实验室,南京,210093 4. 江苏大学化学化工学院,镇江,212013 |
| 基金项目： | 江苏省自然科学基金;江苏省教育厅重大基金 |
| 摘 要： | 以5-[N-乙酸根(4-吡啶基)]四唑为桥联配体，分别与Cu(ClO)2·6H2O和CdCl2的水溶液反应，获得配聚物[Cu(a4-ptz)2·2H2O]n (1)和[{Cd(a4-ptz)·(H2O)2Cl}·H2O]n (2)，2个化合物通过元素分析、IR、TGA等表征，并测定了它的晶体结构。结果表明：化合物1是一个二维四方格子结构的配位聚合体，化合物2含有四元环(Cd2Cl2)的一维Z-型聚合链。化合物2在280 ℃以下热稳定性好，并且不溶于一般溶剂，因此可成为潜在的荧光材料。 |
| 关 键 词： | 铜(Ⅱ)； 镉(Ⅱ)； 四唑； 配聚物； 晶体结构； 发光 |
| 文章编号： | 1001-4861（2007）11-1887-08 |
| 修稿时间： | 2007-06-18 |
New Cu(Ⅱ) and Cd(Ⅱ) Coordination Polymers Employing 5-[N-acetato(4-pyridyl)] Tetrazolate as a Bridging Ligand |
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| YANG Gao-Wen,LI Qiao-Yun,WANG Jun,YUAN Rong-Xin and XIE Ji-Min. New Cu(Ⅱ) and Cd(Ⅱ) Coordination Polymers Employing 5-[N-acetato(4-pyridyl)] Tetrazolate as a Bridging Ligand[J]. Chinese Journal of Inorganic Chemistry, 2007, 23(11): 1887-1894 | |
| Authors: | YANG Gao-Wen LI Qiao-Yun WANG Jun YUAN Rong-Xin XIE Ji-Min |
| Affiliation: | Department of Chemistry & Materials Engineering, Jiangsu Laboratory of Advanced Functional Materials, Changshu Institute of Technology, Changshu, Jiangsu 215500,Department of Chemistry & Materials Engineering, Jiangsu Laboratory of Advanced Functional Materials, Changshu Institute of Technology, Changshu, Jiangsu 215500,Department of Chemistry & Materials Engineering, Jiangsu Laboratory of Advanced Functional Materials, Changshu Institute of Technology, Changshu, Jiangsu 215500;School of Chemistry, Jiangsu University, Zhenjiang, Jiangsu 212013,Department of Chemistry & Materials Engineering, Jiangsu Laboratory of Advanced Functional Materials, Changshu Institute of Technology, Changshu, Jiangsu 215500;State Key Laboratory of Coordination Chemistry, Institute of Coordination Chemistry, Nanjing U and School of Chemistry, Jiangsu University, Zhenjiang, Jiangsu 212013 |
| Abstract: | Two coordination polymers [Cu(a4-ptz)2· 2H2O]n (1) and [{Cd(a4-ptz)· (H2O)2Cl}· H2O]n (2) were synthesized and characterized by elemental analysis, IR spectroscopy, thermal analysis, and X-ray crystal structure analysis.Complex 1 exhibits a 2D square grid polymeric structure with dimensions of 1.220 0 nm × 1.220 0 nm. Complex 2possesses a 1D Z-type polymeric chain, which contains four-membered ring (Cd2Cl2). The thermal stability of complex 2 up to about 280 ℃ (TGA measurement) and their insolubility in common solvents make it a good candidate for potential fluorescent materials. CCDC: 658850, 1; 658851, 2. |
| Keywords: | tetrazole coodination polymer crystal structure luminescence |
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