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Direct aqueous injection gas chromatographic analysis of polar compounds using sorbents containing potassium fluoride dihydrate
Authors:B Polanuer
Institution:(1) All-Union Institute for Genetics of Industrial Microorganisms, 1 Dorozny pr., 1, 113545 Moscow, USSR
Abstract:Summary For direct aqueous injection gas-chromatographic analysis of polar compounds present in aqueous solutions sorbents containing conventional stationary phases and potassium fluoride crystal hydrate are proposed. On such sorbents polar compounds elute with narrow symmetrical zones under gentle chromatographic conditions. In such sorbents KF.2H2O mainly deactivates the surface of the solid support. The polarity of these sorbents is compared with the polarity of molten potassium fluoride dihydrate and conventional stationary phases.
Keywords:Gas chromatography  Direct aqueous injection  KF  2H2O containing sorbents
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