Apparatus for High-Resolution Solid Hydrogen Matrix Isolation Spectroscopy and Its Application |
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Authors: | Wenping Deng Gang Xu Lei Wan Anwen Liu Bo Gao Junhe Du Shuiming Hu Yang Chen |
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Affiliation: | aHefei National Laboratory for Physical Sciences at Microscale, Department of Chemical Physics, University of Science and Technology of China, Hefei 230026, P. R. China |
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Abstract: | Apparatus integrating a Fourier transform-infrared (FT-IR) spectrometer and a mid-infrared difference frequency generation (DFG) laser spectrometer was built for the study of the matrix isolation spectrum in solid molecular hydrogen. A 3-cm-long molecular hydrogen crystal was grown in a liquid-helium Dewar, and its infrared absorption spectrum in the 1-5 μm region was recorded to test the system. The W0(0) (ν=0←0, J=6←0) line around 2410 cm−1 of solid hydrogen was investigated with the DFG laser spectroscopy. High-resolution matrix isolation spectrum of CO2 co-deposited with hydrogen on a BaF2 cold plate at liquid-helium temperature was studied. |
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Keywords: | Hydrogen molecule Matrix isolation Fourier transform-infrared spectroscopy Laser difference frequency generation Carbon dioxide |
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