N,N-Di-isopropyl-O,O-Di-p-methoxybenzylphosphoramidite——A New Phosphorylating Reagent |
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作者姓名: | Shoichirol OZAKI Ai You HAO Xiang Zheng KONG Da Xing ZHENG |
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作者单位: | Department of Chemistry,Shandong University,Jinan 250100 |
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摘 要: | Thedibenzyldiisopropylphosphoramidite"',whichcouldbecleavedbyreduction(hydrogenolysis),isaveryusefulreagentforthephosphorylationofhydroxygroupespeciallyvicinalhydroxygroup.Itisusedveryoftenforthesynthesisofnucleotideandmyo-inositolpolyphosphates.However,itcannotbeusedforthephosphorylationofthecompoundshavinganolefinicgroupwhichwouldalsobereducedtoparaffininthereductioncleavingofthebenZylgroup.Now,WereportthesynthesisofanewphosphorylatingreagentN,N-di-isopropyl-O,O-di-P-methox1.Sincep-methox…
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