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Spectroscopic identification of carbon dioxide clusters: (CO2)6 to (CO2)13
Authors:Oliaee J Norooz  Dehghany M  Moazzen-Ahmadi N  McKellar A R W
Institution:Department of Physics and Astronomy, University of Calgary, 2500 University Drive North West, Calgary, Alberta T2N 1N4, Canada.
Abstract:In spite of wide interest in CO(2) clusters, only dimers and trimers have previously been assigned to specific infrared bands. Here, transitions for clusters with 6-13 molecules are identified in the ν(3) region (~2350 cm(-1)). Spectra are observed in a supersonic jet (T ~ 2.5 K) using a tunable laser probe, and analyzed with the aid of cluster calculations based on a widely-used model potential. Vibrational origins show blue-shifts significantly larger than predicted by resonant dipole interactions.
Keywords:
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