Spectroscopic identification of carbon dioxide clusters: (CO2)6 to (CO2)13 |
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Authors: | Oliaee J Norooz Dehghany M Moazzen-Ahmadi N McKellar A R W |
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Institution: | Department of Physics and Astronomy, University of Calgary, 2500 University Drive North West, Calgary, Alberta T2N 1N4, Canada. |
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Abstract: | In spite of wide interest in CO(2) clusters, only dimers and trimers have previously been assigned to specific infrared bands. Here, transitions for clusters with 6-13 molecules are identified in the ν(3) region (~2350 cm(-1)). Spectra are observed in a supersonic jet (T ~ 2.5 K) using a tunable laser probe, and analyzed with the aid of cluster calculations based on a widely-used model potential. Vibrational origins show blue-shifts significantly larger than predicted by resonant dipole interactions. |
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