Application of aminopropyltriethoxysilane and <Emphasis Type="Italic">N</Emphasis>-[2-(aminoethyl)-<Emphasis Type="Italic">N</Emphasis>-3-(trimethoxysilyl)propyl]amine to the synthesis of linear and heterocyclic compounds |
| |
Authors: | A D Kirilin L O Belova A V Gavrilova E A Korobova |
| |
Institution: | (1) Celltech Therapeutics Ltd., Slough, UK; |
| |
Abstract: | Reaction of 3-aminopropyltriethoxysilane and N-2-(aminoethyl)-N-3-(trimethoxysilyl)propyl]-amine and their derivatives with diethylcarbamic acid trimethylsilyl ether and trimetisilylisocyanate
proceeds through the stage of formation of intermediate products which under conditions of the synthesis undergo intramolecular
(in the case of formation O-silylcarbamates) and intermolecular (in the case of the formation of carbamide trimethylsilyl derivatives) desilylation leading
to the cyclic and linear products respectively. |
| |
Keywords: | |
本文献已被 SpringerLink 等数据库收录! |