Structural features and initiating properties of the hexaadduct of polystyryllithium and fullerene C60 in tetrahydrofuran and their role in synthesis of heteroarm star-like polymers |
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Authors: | L V Vinogradova O V Ratnikova E A Butorina D Kukling H -J P Adler |
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Institution: | (1) Institute of Macromolecular Compounds, Russian Academy of Sciences, St. Petersburg, Russia |
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Abstract: | Structural transformations of the hexaadduct of polystyryllithium and fullerene C60 in the course of interaction with a proton donor or 1,1-diphenylethylene and at initiation of styrene polymerization were studied, and their role in the formation of heteroarm star-like polymers with C60 center of branching and arms of polystyrene and poly-2-vinylpyridine was elucidated. |
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