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Synthesis and Thermal Properties of a Novel Nitrogen-containing Epoxy Resin
引用本文:XingHongZHANC HongMeiWAN YuQinMIN ZuoFANC GuoRongQI. Synthesis and Thermal Properties of a Novel Nitrogen-containing Epoxy Resin[J]. 中国化学快报, 2005, 16(4): 547-550
作者姓名:XingHongZHANC HongMeiWAN YuQinMIN ZuoFANC GuoRongQI
作者单位:InstituteofPolymerScience,ZhejiangUniversity,Hangzhou310027
摘    要:A new nitrogen-containing epoxy resin (XT resin) was synthesized from chain extension of xylenephenolformaldehYlde resin (XPF) and triglycidyl isocyanurate (TGIC) in the presence of base catalyst. FT-IR and H-NMR analysis confirmed the chemical structure of XT resin. It was cured with dicyandiamide (DICY) and diaminodiphenyl sulfone (DDS). Dynamic mechanical analysis (DMA) results showed that the introduction of triazine ring provides epoxy polymer with good thermal stability. Furthermore, high char yields at 800℃ in thermogravimetric (TGA)analysis indicated that XT resin had potential flame retardance.

关 键 词:合成方法 热学性质 氮化合物 环氧树脂 热稳定性

Synthesis and Thermal Properties of a Novel Nitrogen-containing Epoxy Resin
Xing Hong ZHANG,Hong Mei WAN,Yu Qin MIN,Zuo FANG,Guo Rong QI? Institute of Polymer Science,Zhejiang University,Hangzhou. Synthesis and Thermal Properties of a Novel Nitrogen-containing Epoxy Resin[J]. Chinese Chemical Letters, 2005, 16(4): 547-550
Authors:Xing Hong ZHANG  Hong Mei WAN  Yu Qin MIN  Zuo FANG  Guo Rong QI? Institute of Polymer Science  Zhejiang University  Hangzhou
Affiliation:Xing Hong ZHANG,Hong Mei WAN,Yu Qin MIN,Zuo FANG,Guo Rong QI? Institute of Polymer Science,Zhejiang University,Hangzhou 310027
Abstract:
Keywords:Nitrogen-containing epoxy resin   xylenephenolformaldehyde resin (XPF)   triglycidyl isocyanurate (TGIC)   thermal stability.
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