Re‐Determination of the Crystal Structure of MIL‐91(Al) |
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| Authors: | Nele Hermer Michael T. Wharmby Norbert Stock |
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| Affiliation: | 1. Institute of Inorganic Chemistry, Christian‐Albrechts‐Universit?t, Kiel, Germany;2. Diamond Light Source Ltd., Harwell Science & Innovation Campus, Didcot, Oxfordshire, UK |
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| Abstract: | The structure of one of the first permanently porous metal phosphonates, MIL‐91(Al) was re‐determined using high resolution synchrotron powder X‐ray diffraction data. The new model is in a lower symmetry space group, with no disordered ligands in the structure, whilst remaining otherwise consistent with the reported compound. New milder synthetic conditions were also developed. |
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| Keywords: | Metal‐organic frameworks Phosphonates Porous materials Rietveld refinement Synchrotron powder X‐ray diffraction |
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