Syntheses,Crystal Structures,and Luminescence Properties of Four Coordination Polymers Based on 1,3,5‐Tris (imidazol‐1‐yl)benzene |
| |
| Authors: | Xinzheng Liu Hongtai Chen Liming Fan Xiutang Zhang |
| |
| Institution: | Advanced Material Institute of Research, College of Chemistry and Chemical Engineering, Qilu Normal University, Jinan, P. R. China |
| |
| Abstract: | Based on the tripodal 1,3,5‐tris(imidazol‐1‐yl)benzene (tib) ligand, four transition metal coordination polymers, namely, {Ni3(tib)2(H2O)12] · (SO4)3}n ( 1 ), {Co1/6(tib)1/3] · (O)1/3}n ( 2 ), and M(tib)(hip)]n (M = Mn for 3 , and M = Co for 4 ) (hip = 5‐hydroxyisophthalic acid), were synthesized through solvothermal method. Their structures were defined by single‐crystal X‐ray diffraction analyses and further characterized by elemental analyses (EA), IR spectra, powder X‐ray diffraction (PXRD), and thermogravimetric analyses (TGA). Complex 1 displays a 2D 3‐connected (63) hcb net. Complex 2 is a 2D (3,6)‐connected (43)2(46.66.83) kgm net. Complex 3 and 4 present similar 2D 4‐connected (44.62) sql net. Moreover, the solid state luminescence properties of complexes 1 and 3 were investigated. |
| |
| Keywords: | 1 3 5‐Tris(imidazol‐1‐yl)benzene 5‐Hydroxyisophthalic acid Solvothermal methods Luminescence properties |
|
|
