Synthesis and Crystal Structures of Copper Zinc Phenylthiolate and the First Copper Zinc Selenolate and Tellurolate Complexes |
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| Authors: | Daniel Fuhrmann Tobias Severin Harald Krautscheid |
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| Institution: | Institut für Anorganische Chemie, Fakult?t für Chemie und Mineralogie, Universit?t Leipzig, Leipzig, Germany |
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| Abstract: | Five copper zinc phenylchalcogenolate complexes (iPr3PCu)3(ZnMe2)2(SPh)3] ( 1 ), (iPr3PCu)2(ZnPh)4(SPh)6] ( 2 ), (iPr3PCu)2(ZnEt)4(SPh)6] ( 3 ), (iPr3PCu)3(ZnEt)(SePh)4] ( 4 ), and (iPr3PCu)3Cu(iPr3PZn)(TePh)6] ( 5 ) were synthesized by the reaction of phosphine stabilized copper phenylchalcogenolate complexes with ZnR2 (R = Me, Et, Ph) with and without additional chalcogenol. The novel mixed metal compounds were characterized by single‐crystal X‐ray structure analysis and NMR spectroscopy. 4 and 5 are the first examples of compounds with a Zn–Se–Cu or a Zn–Te–Cu linkage, respectively. |
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| Keywords: | Copper zinc phenylchalcogenolates Crystal structures Coordination chemistry Copper Zinc |
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