Acid-catalyzed reactions of thiocyanates with camphene |
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| Authors: | A V Arkhipova K V Malkova T N Sokolova V R Kartashov |
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| Institution: | 1.Nizhni Novgorod State Technical University,Nizhni Novgorod,Russia |
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| Abstract: | The reactions of thiocyanates with camphene catalyzed by the heteropoly acids H3PW12O40 and H4SiW12O40 were studied. The optimal reaction conditions were found, and the formation of N-substituted thiocarbamates in comparatively high yields was established. It was shown that the heteropoly acids exhibit a higher catalytic activity than sulfuric acid. |
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