Hydrolysis of 2-acetyl-substituted fluoroalkyl 3-ketoesters |
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| Authors: | V. M. Krokhalev V. I. Saloutin K. I. Pashkevich |
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| Affiliation: | (1) Institute of Chemistry, Urals Science Center, Academy of Sciences of the USSR, Sverdlovsk |
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| Abstract: | Conclusions Fluoroalkyl 2-acetyl-3-ketoesters are hydrolyzed by a) aqueous KOH regioselectively with cleavage of the C2-C3 bond, b) aqueous ethanolic KOH and aqueous pyridine with cleavage of the C2-C3 and C2-C4 bonds, and c) in neutral aqueous and acid media with cleavage of the C1-C2 and C2-C4 bonds.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2112–2113, September, 1987. |
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