Benzyne-induced ring opening reaction of thiiranes. Efficient synthesis of phenyl vinyl sulfides |
| |
| Authors: | Juzo Nakayama Satoshi Takeue Masamatsu Hoshino |
| |
| Institution: | Department of Chemistry, Faculty of Science, Saitama University, Urawa, Saitama 338, Japan |
| |
| Abstract: | A series of thiiranes react with benzyne to provide an efficient synthesis of phenyl vinyl sulfides. The reaction is stereospecific, thus producing cis-(phenylthio)-stilbene from cis-2,3-diphenylthiirane and trans-(phenylthio)stilbene from trans-2,3-diphenylthiirane. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
