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The ortho-lithiation of phenyl groups and α-lithiation of alkyl groups of thiophosphoryl compounds
Authors:Masaaki Yoshifuji  Tadao Ishizuka  Yoon Jung Choi  Naoki Inamoto
Affiliation:Department of Chemistry, Faculty of Science, The University of Tokyo, Hongo, Tokyo 113, Japan
Abstract:Diphenylphosphinothioyl compounds were ortho-lithiated and alkyldiphenyl phosphine sulfides were α-lithiated and the resulting lithio compounds reacted to give the corresponding o- and α-substituted products.
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