Un dienophile chiral tres reactif : le Z-(R)S p-tolylsulfinyl-3 propenoate de methyle |
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| Authors: | Christian Maignan Ahmed Guessous Francis Rouessac |
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| Affiliation: | E.R.A. 07.0394, Laboratoire de Synthèse Organique, Faculté des Sciences B.P. 41, 72017 Le Mans Cedex, France |
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| Abstract: | Methyl Z-(R)S 3-p-tolylsulfinyl propenoate reacts under mild conditions with cyclopentadiene. A high stereoselectivity and diastereospecificity were observed. The structure and absolute stereochemistry were established by N.M.R. |
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