Automerizations in benzenoid hydrocarbons. New mechanistic insights from the thermal rearrangement of benz[a]anthracene-5-13C. |
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| Authors: | Lawrence T. Scott Tsze-Hong Tsang Louis A. Levy |
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| Affiliation: | Department of Chemistry, University of Nevada, Reno, Nevada 89557 U.S.A.;National Institute of Environmental Health Sciences, P.O. Box 12233, Research Triangle Park, North Carolina 27709 U.S.A. |
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| Abstract: | Scrambling of the carbon atoms in benz[a]anthracene between positions 5 and 6 has been shown to occur at high temperatures; a mechanism involving thermal generation of a carbene is proposed. |
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