Pheromone synthesis—63 Synthesis of both the enantiomers of 2,3-dihydro-2- isopropyl-2,5-dimethylfuran,a sex specific compound in females of the beetle hylecoetus dermestoidesL |
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| Authors: | Kenji Mori Takashi Ebata Shozo Takechi |
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| Affiliation: | Department of Agricultural Chemistry, The University of Tokyo, Yayoi 1-1-1, Bunkyo-ku, Tokyo 113, Japan |
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| Abstract: | Both the enantiomers of 2,3-dihydro-2-isopropyl-2,5-dimethylfuran were synthesized employing the Sharpless asymmetric epoxidation reaction. The (R)-(—)-enantiomer of this cyclic enol ether was also synthesized starting from (R)-(—)-linalool. |
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