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Carbethoxyallylation using radical chemistry
Authors:Derek H.R. Barton  David Crich
Affiliation:Institut de Chimie des Substances Naturelles, C.N.R.S., 91190 Gif-sur-Yvette, France
Abstract:Radicals derived from the esters of N-hydroxy-2-thiopyridone react smoothly in a concerted reaction with 2-carbethoxy-3-t-butylhioprop-1-ene to give the corresponding 2-carbethoxyallyl derivatives with shift of the double bond.
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