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Anomeric effect of radicals
Authors:B. Giese  J. Dupuis
Affiliation:Institut für Organische Chemie und Biochemie Technische Hochschule Darmstadt Petersenstraβe 22, D-6100 Darmstadt, Germany
Abstract:The glucosyl radical 1 is attacked predominately at the axial position. This can be explained by an anomeric effect that stabilizes σ-radical 5.
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