Anomeric effect of radicals |
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Authors: | B. Giese J. Dupuis |
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Affiliation: | Institut für Organische Chemie und Biochemie Technische Hochschule Darmstadt Petersenstraβe 22, D-6100 Darmstadt, Germany |
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Abstract: | The glucosyl radical 1 is attacked predominately at the axial position. This can be explained by an anomeric effect that stabilizes σ-radical 5. |
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