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An esr study of the photoreaction of nitroalkanes with tetraphenylbiphosphine and tetraethylpyrophosphite |
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| Authors: | Angelo Albbrti Andrew Hudson Gian Franco Pedulli |
| Affiliation: | Istituto dei Composti del Carbonio Contenenti Eteroatomi e loro Applicazioni, C.N.R., 40064 Ozzano Emilia Italy;School of Chemistry and Molecular Sciences, University of Sussex, Brighton BN1 9QJ, U.K.;Istituto di Chimica Organica, Universitá, 09100 Cagliari Italy |
| Abstract: | Some paramagnetic species formed in the photoreactions of nitroalkanes with P-compounds have been characterized by ESR. The observed radicals are mostly nitroxides whose structures are consistent with the trapping of P-centred radicals by intermediate nitroso compounds. |
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