Ligand effect in epoxidatidns by hydroperoxides using molybdenum catalyst: epox idation of 3-carene |
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| Authors: | V.P. Rajan S.N. Bannore H.N. Subbarao Sukh Dev |
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| Affiliation: | Malti-Chem Research Centre, Nandesari, Vadodara India |
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| Abstract: | Epoxidation of (+)-3-carene with pinane hydroperoxide in presence of various transition metal catalysts, has been evaluated as a preparative method for (+)-3α,4α-epoxycarane. Catalysts based on Mo(VI) were found to be most suitable. A distinct ligand effect was noted for this oxidation and a plausible rationale is put forward. |
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