The cope rearrangement in substituted semibullvalenes as studied by dynamic 13C NMR |
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| Authors: | C Schnieders K Müllen C Braig H Schuster J Sauer |
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| Institution: | Institut für Organische Chemie der Universität Köln, Greinstr. 4, D-5000 Köln West-Germany;Institut für Organische Chemie der Universität Regensburg, Universitätsstr. 31, D-8400 Regensburg West-Germany |
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| Abstract: | NMR-data for some substituted semibullvalenes are reported and the Cope rearrangement is analysed kinetically. Substituent effects on the activation barriers are discussed. |
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