Synthesis of naturally occurring brassinosteroids employing cleavage of 23,34-epoxides as key reactions. Synthesis of brassinolide,castasterone, dolicholide,dolichosterone, homodolicholide,homodolichosterone, 6-deoxocastasterone and 6-deoxodolichosterone |
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| Authors: | Kenji Mori Masayuki Sakakibara Katsuhide Okada |
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| Institution: | Department of Agricultural Chemistry, The University of Tokyo, Yayoi 1-1-1, Bunkyo-ku, Tokyo 113, Japan |
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| Abstract: | Eight new plant growth-promoting steroids (brassinolide, castasterone, dolicholide, dolichosterone, homodolicholide, homodolichosterone, 6-deoxocastasterone and 6-deoxodolichosterone) were synthesized by the regio- and stereoselective ring-opening reactions of 23,24-epoxides prepared from stigmasterol. |
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