The X-ray structure of methyl shoreate and the stereochemistry of eichlerianic acid,cabraleone and ocotillone |
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Authors: | David Lavie Felix Frolow Haim Meshulam |
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Institution: | Departments of Organic and Structural Chemistry, The Weizmann Institute of Science, Rehovot Israel |
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Abstract: | An X-ray structure determination of methyl shoreate has shown that this compound has 20S,24R stereochemistry in the side chain. Ocotillone therefore possesses the same configuration, whereas eichlerianic acid and cabraleone must have 20S,24S stereochemistry. A previous wrong assignment is thereby corrected. |
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