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Diprotonation of nitroarenes
Authors:Toshiharu Ohta  Koichi Shudo  Toshihiko Okamoto
Affiliation:Faculty of Pharmaceutical Sciences, University of Tokyo 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113, Japan
Abstract:Cryoscopic measurement shows that 1-nitronaphthalene is diprotonated in trifluoromethanesulfonic acid (TFSA). The diprotonated nitronaphthalenes are N,N-dihydroxyiminium-naphthalenium dications, which is fully characterized by UV, 1H-, 13C and 15N-NMR spectra.
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