Bile pigment studies-VII New syntheses of biliverdin-IXα dimethyl ester and two related mono-vinyl-mono-ethyl isomers |
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| Authors: | Kevin M Smith Ravindra K Pandey |
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| Institution: | Department of Chemistry, University of California, Davis CA 95616, U.S.A. |
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| Abstract: | Using the recently developed route through di-t-butyl b-bilene-1,19-dicarboxylates, new syntheses of biliverdin-IXα dimethyl ester (1) and two related mono-vinyl-mono-ethyl isomers (2) and (3), are described. The two dihydro-derivatives of (1) are important in connection with biosynthetic studies of the origin of algal biliproteins. |
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