A highly regio- and stereoselective synthesis of internal olefins via an elimination of trimethylstannyl group |
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| Authors: | Eigoro Murayama Masahiro Uematsu Hiroyuki Nishio Tadashi Sato |
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| Affiliation: | Department of Applied Chemistry, Waseda University, Ookubo 3, Shinjuku-ku, Tokyo 160, Japan |
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| Abstract: | Internal reaction of secondary alkyltin(IV) compounds having thionium ion gave internal trans olefins with high yield and regio- and stereoselectivity via 1,5- or 1,6-transfer of a hydride β to the trialkylstannyl group. |
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