A new method of synthesis of stereospecifically 7,7-difunctionalized bicyclo [2.2.1]Heptene derivatives |
| |
| Authors: | AG González J Darias F Díaz |
| |
| Institution: | Instituto de Productos Naturales Orgánicos, CSIC, La Laguna; Instituto de Química Orgánica, Universidad de La Laguna, Teneriffe, Canary Islands, Spain |
| |
| Abstract: | The cyclopropyl carbinol group of the adducts 7a and 7b undergoes anchimerically-assisted solvolytic ring opening, leading to a stabilized 7-norbornenyl cation which collapses, stereospecifically, to 7,7-difunctionalized bicyclic/2.2.1/heptene derivatives 8 and 9. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
