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Silafunctional compounds in organic synthesis. 21. Hydrogen peroxide oxidation of alkenyl(alkoxy)silanes
Authors:Kohei Tamao  Makoto Kumada  Kimio Maeda
Institution:Department of Synthetic Chemistry, Kyoto University, Yoshida, Kyoto 606, Japan;Department of Industrial Chemistry, Kochi Technical College, Monobe, Nankoku 783, Japan
Abstract:The carbon-silicon bond in alkenyl(alkoxy)silanes is readily cleaved by hydrogen peroxide to form the corresponding aldehydes, carboxylic acids or ketones, depending upon the nature of the alkenyl group and the reaction conditions.
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