On the rearrangement in carbonyl oxide intermediates |
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Authors: | Yasuhiko Sawaki Katsuya Ishiguro |
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Affiliation: | Department of Applied Chemistry, Faculty of Engineering, Nagoya University, Chikusa-ku, Nagoya 464, Japan |
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Abstract: | Sensitized photooxidation of alkylphenyldiazomethanes under oxygen afforded, in addition to alkyl phenyl ketones, alkyl benzoates, which are probably formed by a rearrangement via dioxirane diradical. |
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