|
|||||
|
|
A vinylsilane route to trans-7a-methylhydrind-4-en-1,6-dione |
|
| Authors: | Scott E Denmark Juris P Germanas |
| Institution: | Roger Adams Laboratory, School of Chemical Sciences, University of Illinois, Urbana, Illinois 61801 U.S.A |
| Abstract: | A stereoselective synthesis of the title compound is described. The overall yield is 34% starting with 2-methyl-2-cyclopentenone. The trans ring-fusion stereochemistry is established by a conjugate addition/trapping sequence. |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ | |