Le cation méthylènecyclopropyle: Etude théorique. Solvolyse des halogénocyclopropènes et des halogénométhylenecyclopropanes |
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Authors: | R. Arnaud A. Dussauge H. Faucher R. Subra M. Vidal M. Vincens |
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Affiliation: | Laboratoire d''Etudes Dynamiques et Structurales de la Sélectivité, Université Scientifique et Médicale de Grenoble, B.P. 53X, 38041 Grenoble Cedex France |
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Abstract: | The solvolysis in acid solution of allylic halides and acetates of methylenecyclopropanes and cyclopropylmethanes does not lead to ring opening when there is an ethoxycarbonyl substituent on the ring methylene. Only the cyclopropenyl derivative is obtained. A study of the electronic structure and the geometry of the possible allylic cation intermediate has been carried out using the MNDO method. In addition, the influence of the substituents on the ring opening of this cation has beeen examined. It appears that the ring opening is disfavoured upon substitution of an alkyl group by alkoxymethyl on the ring methylene group. |
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