Synthesis of enol ethers from lactones using modified Julia olefination reagents: application to the preparation of tri- and tetrasubstituted exoglycals |
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Authors: | Benjamin Bourdon |
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Affiliation: | ICBMS, Université Claude Bernard Lyon 1, Laboratoire de Chimie Organique 2—Glycochimie, UMR-CNRS 5246, Bâtiment 308, 43 Boulevard du 11 Novembre 1918, F-69622 Villeurbanne, France |
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Abstract: | A new route to substituted exoglycals from the corresponding lactones is described. The enol ethers synthesis via a modified Julia olefination of sugar-derived lactones is extended to substituted benzothiazolyl sulfones to furnish tri- and tetrasubstituted exoglycals. |
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Keywords: | Julia olefination Exoglycals Lactones Enol ethers |
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