The efficient synthesis of unsymmetrical oligo(phenylenevinylenes) |
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| Authors: | Timothy Smith |
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| Affiliation: | Department of Chemistry and The Center for Laser and Optical Spectroscopy, The University of Akron, Akron, OH 44325-3601, United States |
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| Abstract: | Selective DDQ oxidation of 2,5-bis(methylmethoxy)-1,4-di(octyloxy)benzene generates an unsymmetrical subunit suitable for the preparation of substituted tetrameric oligo(phenylenevinylenes) in good to excellent yields. |
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| Keywords: | Oligomers Phenylene vinylene Asymmetric synthesis Photovoltaic Wittig Horner-Wadsworth-Emmons Mono-formylated Coupling |
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