Hydrothermal synthesis of [Mn(HTPO)(BIPY)] (H3TPO = tris-(4-carboxylphenyl)phosphine oxide): a crosslinked coordination polymer |
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| Authors: | M. John Plater Mark R. St J. Foreman Janet M.S. Skakle |
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| Affiliation: | (1) Department of Chemistry, Beijing Normal University, Beijing, 100875, People's Republic of China;(2) State Key laboratory of Rare Earth Materials Chemistry and Applications, Department of Chemistry, Peking University, Beijing, 100871, People's Republic of China |
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| Abstract: | The hydrothermal synthesis and crystal structure of the title compound is reported. The structure consists of 1-D looped chains with the HTPO ligand binding through the phosphoryl and two carboxylate oxygens to manganese atoms. The carboxylic acid group is hydrogen bonded to adjacent chains forming a 2-D hydrogen bonded network. The crystals are triclinic and the space group isP-1 with a = 11.6767(8) Å, b = 10.8680(8) Å and c = 11.4232(87rpar; Å  = 92.301(2)°,  = 106.932(2)° and  = 103.2390(10)° V = 1341.02(16) Å3; Z = 2. |
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| Keywords: | Coordination polymer manganese hydrogen bonding hydrothermal synthesis |
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