Structure and catalytic activity of metal complexes on carriers 3. Rhodium complexes on modified polymers and their catalytic properties in the reduction of nitrobenzene by chemically bound hydrogen |
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| Authors: | V. F. Dovganyuk V. Z. Sharf V. K. Belyaeva I. N. Marov Zh. L. Dykh L. I. Lafer V. I. Yakerson |
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| Affiliation: | (1) N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, Moscow;(2) V. I. Vernadskii Institute of Geochemistry and Analytical Chemistry, Academy of Sciences of the USSR, Moscow |
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| Abstract: | Heterogenized catalysts based on rhodium complexes attached to polymers modified by the groups 3(5)-methylpyrazole, imidazole and benzimidazole have been synthesized. The process of their formation has been investigated by IR, UV, and EPR spectroscopy. Results have been obtained for the catalytic activity of the complexes in the hydrogenation of nitrobenzene by hydrogen transfer from propan-2-ol and NaBH4.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, pp. 268–273, February, 1990. |
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