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Bis(trifluoromethyl)-containing 1-azatricycloheptanes |
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| Authors: | V M Nagaev G A Sokolsky S S Khokhlov A F Yeleyev |
| Institution: | (1) State Scientific Center of the Russian Federation “State Scientific Research Institute of Organic Chemistry and Technology”, 23 sh. Entuziastov, 111024 Moscow, Russian Federation |
| Abstract: | Methods for the synthesis ofanti-3-halo-7, 7-bis(trifluoromethyl)-1-azatricyclo2.2.1.02,6]heptanes by conjugated halogenation of 3,3-bis(trifluoromethyl)-2-azabicyclo2.2.1]hept-5-ene have been developed. Hydrohalogenation of the synthesized 1-azatricyclic compounds gives exclusively 6,7-dihalo-3,3-bis(trifluoromethyl)-2-azabicyclo2.2.1]heptanes. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 9, pp. 1649–1653, September, 1997. |
| Keywords: | 2-azabicycloheptanes conjugated halogenation 1-azatricycloheptanes hydrohalogenation rearrangements “ nonclassical” cation |
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