| 温和条件下液态醇催化氧化制醛、酮 |
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| 引用本文： | 陈琳,许传芝,夏春谷,冯艳华.温和条件下液态醇催化氧化制醛、酮[J].化学进展,2004,16(5):758-765. |
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| 作者姓名： | 陈琳 许传芝 夏春谷 冯艳华 |
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| 作者单位： | 中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室,兰州,730000;兰州大学化学化工学院,兰州,730000 |
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| 摘 要： | 本文对温和条件下液态醇催化氧化制醛或酮的研究进展进行了全面评述,介绍了均相催化剂、液固多相催化剂、有机相-水相两相催化剂、氟两相催化剂和离子液相催化剂,着重讨论了以O_2为氧源的催化体系.
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| 关 键 词： | 液态醇 催化氧化 均相催化 液固多相催化 水-有机两相催化 氟两相催化 离子液催化 |
| 文章编号： | 1005-281X(2004)05-0758-08 |
| 收稿时间： | 2003-09-01 |
| 修稿时间： | 2003年9月1日 |
Advances in Oxidations of Liquid Alcohols into the Corresponding Carbonyls under Mild Conditions |
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| Chen Lin,Xu Chuanzhi,Xia Chungu,Feng Yanhua.Advances in Oxidations of Liquid Alcohols into the Corresponding Carbonyls under Mild Conditions[J].Progress in Chemistry,2004,16(5):758-765. |
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| Authors: | Chen Lin Xu Chuanzhi Xia Chungu Feng Yanhua |
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| Institution: | (State Key Laboratory of Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
College of Chemistry & Chemical Engineering, Lanzhou University;Lanzhou 730000, China) |
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| Abstract: | A review is presented on the progress in catalytic oxidation of liquid alcohols into the corresponding carbonyls under mild conditions. The homogeneous catalysts,liquid solid heterogeneous catalysts,organic/aqueous biphasic catalysts,flourous biphasic catalysts and ionic liquid phase catalysts are descrided. The emphasis is placed on the catalytic systems with O 2 as the oxidant. |
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| Keywords: | liquid alcohol catalytic oxidations homogeneous catalysis liquid-solid heterogeneous catalysis organic/aqueous biphasic catalysis flourous biphasic catalysis ionic liquid catalysis |
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