| Synthesis and Crystal Structure of a Cr（Ⅲ） Dimer [Cr2（8-hqn）2Cl4（H2O）2]·2（CH3）2CO （8-hqn = 8-Hydroxyoxyquinolate） |
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| 引用本文： | 鲁祥勇,杨红领,陈学太. Synthesis and Crystal Structure of a Cr（Ⅲ） Dimer [Cr2（8-hqn）2Cl4（H2O）2]·2（CH3）2CO （8-hqn = 8-Hydroxyoxyquinolate）[J]. 结构化学, 2009, 28(6): 673-676 |
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| 作者姓名： | 鲁祥勇 杨红领 陈学太 |
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| 作者单位： | Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering,Nanjing University, Nanjing 210093, China |
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| 摘 要： | The title complex [Cr2（8-hqn）2Cl4（H2O）2]·2（CH3）2CO （8-hqn = 8-hydroxyoxyquinolate） has been synthesized and characterized by single-crystal X-ray diffraction. It crystallizes in the triclinic system, space group P^-1 with a = 8.719（1）, b = 9.226（1）, c = 9.717（1） A^°, α = 71.916（2）, β= 78.072（2）, γ = 76.014（2）°, V= 713.72（15） A^°^3, Z= 1, Dc= 1.597g/cm^3, F（000） = 350 and μ（MoKa） = 1.177 mm^-1, the final R = 0.0490 and wR = 0.1055 for 1616 observed reflections with I 〉 2σ（I）. It is a dimer constructed by two monomeric units [Cr（8-hqn）Cl2（H2O）] bridged by phenoxide-like oxygen atom from 8-hydroxyoxyquinolate, where the two six-coordinated Cr（Ⅲ）atoms exhibit an octahedral coordination geometry.
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| 关 键 词： | CR2 二聚体 晶体结构 Cr 合成 水 射线衍射 三斜晶系 |
Synthesis and Crystal Structure of a Cr(Ⅲ) Dimer [Cr2(8-hqn)2Cl4(H2O)2]·2(CH3)2CO (8-hqn = 8-Hydroxyoxyquinolate) |
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| LU Xiang-Yong,YANG Hong-Ling,CHEN Xue-Tai. Synthesis and Crystal Structure of a Cr(Ⅲ) Dimer [Cr2(8-hqn)2Cl4(H2O)2]·2(CH3)2CO (8-hqn = 8-Hydroxyoxyquinolate)[J]. Chinese Journal of Structural Chemistry, 2009, 28(6): 673-676 |
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| Authors: | LU Xiang-Yong YANG Hong-Ling CHEN Xue-Tai |
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| Affiliation: | Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering,Nanjing University, Nanjing 210093, China |
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| Abstract: | The title complex [Cr2(8-hqn)2Cl4(H2O)2]·2(CH3)2CO (8-hqn = 8-hydroxyoxyquino-late) has been synthesized and characterized by single-crystal X-ray diffraction. It crystallizes in the trielinic system, space group P1 with a = 8.719(1), b = 9.226(1), c = 9.717(1) A, α=71.916(2), β= 78.072(2), γ = 76.014(2)°, V = 713.72(15) A3, Z = 1, Dc = 1.597g/cm3, F(000) = 350 and μ(MoKa) = 1.177 mm-1, the final R = 0.0490 and wR = 0.1055 for 1616 observed reflections with I > 2σ(I). It is a dimer constructed by two monomerie units [Cr(8-hqn)Cl2(H2O)] bridged by phenoxide-like oxygen atom from 8-hydroxyoxyquinolate, where the two six-coordinated Cr(Ⅲ)atoms exhibit an oetahedral coordination geometry. |
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| Keywords: | 8-hydroxyquinoline crystal structure dimer |
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