Lanthanide luminescent anion sensing: evidence of multiple anion recognition through hydrogen bonding and metal ion coordination |
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| Authors: | dos Santos Cidália M G Fernández Pablo Barrio Plush Sally E Leonard Joseph P Gunnlaugsson Thorfinnur |
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| Institution: | School of Chemistry, Centre for Synthesis and Chemical Biology, Trinity College Dublin, Dublin 2, Ireland. |
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| Abstract: | The delayed lanthanide luminescence of the terbium Tb(III)] diaryl-urea complex 1xTb is significantly enhanced upon sensing of dihydrogenphosphate (H2PO4(-)) in CH3CN, which occurs through multiple anion binding through hydrogen bonding interactions and potential metal ion coordination to Tb(III). |
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