Estimation of the kinetic characteristics of sorption of an organic ion on a heterogeneous crosslinked polymer sorbent within the framework of a bidisperse model

For the sorption of rubomycin, an antitumor athracycline-type antibiotic, on BDM-12 carboxyl-containing heterogeneous crosslinked polymer sorbent, it was shown that the measured time dependences of the extent of process are determined by two characteristic times: τ₁ (in the range of short times) and τ₂ (at long times). A phenomenological theory of the kinetics of sorption on the heterogeneous sorbent was developed on the basis of a biporous sorbent model. The dependences of the characteristic times τ₁ and τ₂ on the sorbent grain radius were obtained. It was concluded that the theory makes predictions in good agreement with experimental data and allows calculating the most important kinetic parameters of sorption of organic ions on polymer sorbents: the time of diffusion of the sorbate into microgranules, the diffusion coefficient of the sorbate in transport pores, the effective coefficient of the sorbate diffusion into the heterogeneous sorbent, etc.