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A new nanocluster carbyne-based material synthesized under high pressure
Authors:S V Demishev  A A Pronin  N E Sluchanko  N A Samarin  V V Glushkov  A G Lyapin  M V Kondrin  V V Brazhkin  T D Varfolomeeva  S V Popova  H Ohta
Institution:(1) General Physics Institute, Russian Academy of Sciences, Moscow, 117942, Russia;(2) Institute of High Pressure Physics, Russian Academy of Sciences, Troitsk, Moscow oblast, 142092, Russia;(3) Molecular Photoscience Research Center and Department of Physics, Kobe University, Rokkodai, Nada, Kobe 657-8501, Japan
Abstract:The DC and AC conductivities and the magnetoresistance and thermopower of carbyne samples were studied over the temperature range 1.8–300 K at frequencies 10 MHz–1 GHz. It was established that a variation in the fraction of sp 2 bonds in carbynes induces a transition from one-to two-and then to three-dimensional conduction. The physical properties of the new carbyne-based solids may be understood within the model treating carbyne as a nanocluster material based on linear carbon chains and having a characteristic cluster size of 1 to 10 nm.
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