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Water-soluble Porphyrin as Temperature Sensor Based on Fluorescent Enhancement
Authors:FEI Qiang  WANG Chunyu  WANG Baojun  XU Hui  LI Guanghua  HUAN Yanfu  SHAN Hongyan  FENG Guodong
Institution:1. College of Chemistry, Jilin University, Changchun 130021, P. R. China;
2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China
Abstract:A novel water-soluble porphyrin5,10,15,20-tetra(3-ethoxy-4-hydroxy-5-sulfonate)phenyl porphyrin, H2TEHPPS] was designed and synthesized, which could be used as a potential fluorescence sensor to detect tempe- rature changes. The studies were performed in solution phase and the concentration of H2TEHPPS was 2.0×10-5 mol/L. The optical properties of H2TEHPPS were investigated based on the UV and fluorescence spectra. The results show that the fluorescence intensity of H2TEHPPS is directly proportional to temperature in the range of 293―353 K. So H2TEHPPS can be used as a molecular temperature sensor in biomedical and other fields.
Keywords:Water-soluble porphyrin  Enhanced fluorescence effect  Temperature  Sensor
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