| Non-isothermal Decomposition Kinetics of [Cu（en）2H2O] （FOX-7）2·H2O |
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| 引用本文： | ZHANG Yu,;DONG Kaiyue,;QIU Qianqian,;XU Kangzhen,;HE Fei,;SONG Jirong,;ZHAO Fengqi. Non-isothermal Decomposition Kinetics of [Cu（en）2H2O] （FOX-7）2·H2O[J]. 高等学校化学研究, 2014, 30(4): 672-675. DOI: 10.1007/s40242-014-3549-5 |
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| 作者姓名： | ZHANG Yu, DONG Kaiyue, QIU Qianqian, XU Kangzhen, HE Fei, SONG Jirong, ZHAO Fengqi |
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| 作者单位： | [1]School of Chemical Engineering, Northwest University, Xi 'an 710069, P. R. China; [2]Xi 'an Modern Chemistry Research Institute, Xi 'an 710065, P. R. China |
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| 基金项目： | Supported by the National Natural Science Foundation of China（Nos. 21241003, 20803058）, the Science and Technology Research and Development Program of Shaanxi Province, China（No.2013K02-25） and the Education Committee Foundation of Shaanxi Province, China（No.2013JK0697）. |
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| 摘 要： | The thermal behavior and non-isothermal decomposition kinetics of [Cu（en）2H2O]（FOX-7）2·H2O （en=ethylenediamine） were studied with DSC and TG-DTG methods.The kinetic equation of the exothermal process is dα/dt=（10^17.92/β）4α^3/4exp（-1.688×10^5/RT）.The self-accelerating decomposition temperature and critical temperature of the thermal explosion are 163.3 and 174.8 ℃,respectively.The specific heat capacity of [Cu（en）2H2O]（FOX-7）2·H2O was determined with a micro-DSC method,with a molar heat capacity of 661.6 J·mol^-1·K^-1 at 25 ℃.Adiabatic time-to-explosion was also estimated as 23.2 s.[Cu（en）2H2O]（FOX-7）2·H2O is less sensitive.
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| 关 键 词： | FOX-7 分解动力学 非等温 H2O TG-DTG 铜 DSC法 摩尔热容 |
Non-isothermal Decomposition Kinetics of [Cu(en)2H2O](FOX-7)2·H2O |
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| ZHANG Yu,DONG Kaiyue,QIU Qianqian,XU Kangzhen,HE Fei,SONG Jirong,ZHAO Fengqi. Non-isothermal Decomposition Kinetics of [Cu(en)2H2O](FOX-7)2·H2O[J]. Chemical Research in Chinese University, 2014, 30(4): 672-675. DOI: 10.1007/s40242-014-3549-5 |
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| Authors: | ZHANG Yu DONG Kaiyue QIU Qianqian XU Kangzhen HE Fei SONG Jirong ZHAO Fengqi |
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| Affiliation: | 1. School of Chemical Engineering, Northwest University, Xi'an 710069, P. R. China;
2. Xi'an Modern Chemistry Research Institute, Xi'an 710065, P. R. China |
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| Abstract: | The thermal behavior and non-isothermal decomposition kinetics of [Cu(en)2H2O](FOX-7)2·H2O (en=ethylenediamine) were studied with DSC and TG-DTG methods. The kinetic equation of the exothermal process is dα/dt=(1017.92/β)4α3/4exp(-1.688×105/RT). The self-accelerating decomposition temperature and critical temperature of the thermal explosion are 163.3 and 174.8℃, respectively. The specific heat capacity of [Cu(en)2H2O](FOX-7)2·H2O was determined with a micro-DSC method, with a molar heat capacity of 661.6 J·mol-1·K-1 at 25℃. Adiabatic time-to-explosion was also estimated as 23.2 s. [Cu(en)2H2O](FOX-7)2·H2O is less sensitive. |
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| Keywords: | 1,1-Diamino-2,2-dinitroethylene（FOX-7） Copper complex Non-isothermal decomposition kinetics Thermal property |
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