Study on the preparation of Mg-Li-Ag Alloys by electrochemical deposition from LiCl-KCl-MgCl2-AgCl Melts |
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Authors: | Mi Lin Zhang Peng Cao Wei Han Yong De Yan Li Jun Chen |
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Institution: | 1. Key Laboratory of Superlight Materials and Surface Technology, Ministry of Education, Harbin Engineering University, Harbin, 150001, P. R. China
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Abstract: | Electrochemical deposition of Mg, Li and Ag on molybdenum electrodes in LiCl-KCl-MgCl2-AgCl melts at 943 K to form Mg-Li-Ag alloys was investigated. Cyclic voltammograms (CVs) showed that the potential of Li metal deposition, after the addition of MgCl2 and AgCl, was more positive than that of Li metal deposition before the addition. ??, AgMg4 + ??, and ?? + ?? + LiAg phases of Mg-Li-Ag alloys were obtained by galvanostatic electrolysis. The element Mg distributed homogeneously in the alloys while element Ag mainly located on the grain boundaries. |
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