N-heterocyclic carbene stabilized dichlorosilylene transition-metal complexes of V(I), Co(I), and Fe(0) |
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Authors: | Ghadwal Rajendra S Azhakar Ramachandran Pröpper Kevin Holstein Julian J Dittrich Birger Roesky Herbert W |
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Institution: | Institut für Anorganische Chemie der Universit?t G?ttingen, Tammannstrasse 4, D 37077 G?ttingen, Germany. rghadwal@uni-goettingen.de |
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Abstract: | Reactions of N-heterocyclic carbene stabilized dichlorosilylene IPr·SiCl(2) (1) (IPr = 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) with (η(5)-C(5)H(5))V(CO)(4), (η(5)-C(5)H(5))Co(CO)(2), and Fe(2)(CO)(9) afford dichlorosilylene complexes IPr·SiCl(2)·V(CO)(3)(η(5)-C(5)H(5)) (2), IPr·SiCl(2)·Co(CO)(η(5)-C(5)H(5)) (3), and IPr·SiCl(2)·Fe(CO)(4) (4), respectively. Complexes 2-4 are stable under an inert atmosphere, are soluble in common organic solvents, and have been characterized by elemental analysis and multinuclear ((1)H, (13)C, and (29)Si) NMR spectroscopy. Molecular structures of 2-4 have been determined by single crystal X-ray crystallographic studies and refined with nonspherical scattering factors. |
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