Weak chemiluminescence emission during base induced rearrangement of G-factors |
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| Authors: | Bernat Virginie André Chantal André-Barrès Christiane |
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| Institution: | Laboratoire de Synthèse et de Physicochimie de Molécules d'Intérêt Biologique, UMR CNRS 5068, Université Paul-Sabatier, 118 route de Narbonne, F-31062 Toulouse cedex 04, France. |
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| Abstract: | A rearrangement in basic medium of the natural endoperoxide G3-factor extracted from Eucalyptus grandis is described. Evidence to support a 1,2-dioxetane intermediate that decomposes with weak luminescence emission (quantum yield) is presented. |
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