| A New Inorganic-organic Nanocomposite,4,4''''-Bipyridine Intercalated into Lamellar FePS3 |
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| 引用本文： | Xing Guo CHEN1,Chu Luo YANG1,Jin Gui QIN1*,Kyuya YAKUSHI2,Yasuhiro NAKAZAWA2,Kenji ICHIMURA3 1Department of Chemistry,Wuhan University,Wuhan 430072 2Institute for Molecular Science,Okazaki 444,Japan 3Department of Chemistry,Faculty of Science,Kumamoto University,Kumamoto 860,Japan. A New Inorganic-organic Nanocomposite,4,4''''-Bipyridine Intercalated into Lamellar FePS3[J]. 中国化学快报, 2003, 0(11) |
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| 作者姓名： | Xing Guo CHEN1 Chu Luo YANG1 Jin Gui QIN1* Kyuya YAKUSHI2 Yasuhiro NAKAZAWA2 Kenji ICHIMURA3 1Department of Chemistry Wuhan University Wuhan 430072 2Institute for Molecular Science Okazaki 444 Japan 3Department of Chemistry Faculty of Science Kumamoto University Kumamoto 860 Japan |
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| 作者单位： | Xing Guo CHEN1，Chu Luo YANG1，Jin Gui QIN1*，Kyuya YAKUSHI2，Yasuhiro NAKAZAWA2，Kenji ICHIMURA3 1Department of Chemistry，Wuhan University，Wuhan 430072 2Institute for Molecular Science，Okazaki 444，Japan 3Department of Chemistry，Faculty of Science，Kumamoto University，Kumamoto 860，Japan |
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| 摘 要： | Interest in nanocomposite materials is increased due to their great significance in both fundamental and applied research fields in the past two decades 1. Intercalation of organic species into lamellar inorganic solids provides a useful approach to design and synthesize inorganic-organic nanocomposite materials with novel functional properties compared with the parent compounds 2. The transition metal phosphorous trisulfides, MPS3 (M stands for a metal in +2 oxidation state), are lamellar c…
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A New Inorganic-organic Nanocomposite,4,4''''-Bipyridine Intercalated into Lamellar FePS3 |
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| Xing Guo CHEN,Chu Luo YANG,Jin Gui QIN,Kyuya YAKUSHI,Yasuhiro NAKAZAWA,Kenji ICHIMURA. A New Inorganic-organic Nanocomposite,4,4''''-Bipyridine Intercalated into Lamellar FePS3[J]. Chinese Chemical Letters, 2003, 0(11) |
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| Authors: | Xing Guo CHEN Chu Luo YANG Jin Gui QIN Kyuya YAKUSHI Yasuhiro NAKAZAWA Kenji ICHIMURA |
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| Affiliation: | Xing Guo CHEN1,Chu Luo YANG1,Jin Gui QIN1*,Kyuya YAKUSHI2,Yasuhiro NAKAZAWA2,Kenji ICHIMURA3 1Department of Chemistry,Wuhan University,Wuhan 430072 2Institute for Molecular Science,Okazaki 444,Japan 3Department of Chemistry,Faculty of Science,Kumamoto University,Kumamoto 860,Japan |
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| Abstract: | A new intercalation compound, Fe0.85PS3(4,4-bipyH)0.30 (4,4-bipy = 4,4-bipyridine), is obtained by the intercalation of 4,4-bipyridine?HCl with lamellar FePS3, which is characterized by elemental analysis, powder X-ray diffraction, infrared spectroscopy. By comparison with the pure FePS3, the lattice spacing of Fe0.85PS3(4,4-bipyH)0.30 is expanded by ~ 5.7 , indicating that the ring plane of the guest is perpendicular to the layer of the host. The magnetic property of Fe0.85PS3(4,4-bipyH)0.30 is studied with SQUID. It exhibits an antiferromagnetic phase transition with TN of about 70 K. |
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| Keywords: | Intercalation lamellar FePS3 magnetic property. |
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