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| 四硫富瓦烯及其衍生物在分子开关领域的研究进展 | |
| 引用本文： | 朱玉兰,周鑫鑫,尹起范,曹丽.四硫富瓦烯及其衍生物在分子开关领域的研究进展[J].有机化学,2009,29(1):34-43. |
| 作者姓名： | 朱玉兰 周鑫鑫 尹起范 曹丽 |
| 作者单位： | 1. 淮阴师范学院化学系,江苏省低维材料化学重点建设实验室,淮安,223300;延边大学理学院化学系,延吉,133002 2. 淮阴师范学院化学系,江苏省低维材料化学重点建设实验室,淮安,223300 |
| 基金项目： | 国家自然科学基金，江苏省科技厅自然科学基金 |
| 摘 要： | 四硫富瓦烯(TTF)及其衍生物由于具有特殊的结构和性质, 在分子开关、分子传感器、光信息存储和非线性光学等领域显示出诱人的应用前景. 综述了近几年TTF及其衍生物在分子开关领域的最新研究进展. |
| 关 键 词： | 四硫富瓦烯 合成 分子开关 分子识别 |
| 收稿时间： | 2008-1-24 |
| 修稿时间： | 2008-4-30 |
Advance in Tetrathiafulvalene and Its Derivatives as Molecular Switches |
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| Zhu,Yulan,Zhou,Xinxin,Yin,Qifan,Cao,Li.Advance in Tetrathiafulvalene and Its Derivatives as Molecular Switches[J].Chinese Journal of Organic Chemistry,2009,29(1):34-43. | |
| Authors: | Zhu Yulan Zhou Xinxin Yin Qifan Cao Li |
| Institution: | (a Jiangsu Key Laboratory for Chemistry of Low-dimensional Materials, Department of Chemistry, Huaiyin Teacher’s College, Huai’an 223300) (b Department of Chemistry, College of Science, Yanbian University, Yanji 133002) |
| Abstract: | Tetrathiafulvalene (TTF) and its derivatives can be reversibly transformed into the radical cation TTF•+ and dication TTF2＋ through either chemical or electrochemical oxidation. By using of this feature, TTF and its derivatives have been widely investigated for their potential use in molecular switches, molecular sensors, optical information storage and nonlinear optics etc. This article reviews the recent progress in TTF and its derivatives as molecular switches such as fluorescence switch, photochromism switch, chiral switch and supramolecular switch. |
| Keywords: | tetrathiafulvalene synthesis molecular switch molecular recognition |
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